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International Journal of Applied Chemical and Biological Sciences

ISSN: 2582-788X (Online)

International Journal of Applied Chemical and Biological Sciences
Home Archive Volume 2 - Issue 4 Synthesis of a New Ligand Tris (2-pyridylmethyl) amine functionalized by a methoxy group and study of Dichloroferrous complexes, its reactivity to dioxygen both in the presence and absence of substrate

Volume 2   Issue 4

Research Article

Synthesis of a New Ligand Tris (2-pyridylmethyl) amine functionalized by a methoxy group and study of Dichloroferrous complexes, its reactivity to dioxygen both in the presence and absence of substrate

Article Identifier: https://identifier.visnav.in/1.0001/ijacbs-21f-07003/
Abstract

The biomimetic oxidations at active sites of iron proteins involve peroxides, especially hydrogen peroxide which is a strong and very convenient reagent since it is inexpensive and does not release any toxic by-products. In many cases however, Mother Nature uses molecular dioxygen to carry out major oxidation reactions in particularly attractive conditions. The biomimetic interest of iron complexes in the tris (2-pyridylmethyl) amine series (TPA) is no longer to demonstrate. Various α-substituted TPA-based ligands were prepared with the idea to modulate the electronic properties at the metal centre. A new type of ligand MeOTPA was prepared and the effect of (MeO) in the oxygenation of complex was studied

Keywords: Biomimetic, tris (2-pyridylmethyl) amine, iron(II), Molecular dioxygen activation
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